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Ji-Guang Gu Shu-Pei Cheng Jianhua Liu Ji-Dong Gu 《Journal of Polymers and the Environment》2000,8(4):167-174
An electrochemical impedance spectroscopy (EIS) technique was evaluated for monitoring microbial degradation of electronic packaging polyimides. The microbial inoculum was a mixed culture of fungi isolated previously from deteriorated polyimides. The active fungal consortium comprised Aspergillus versicolor, Cladosporium cladosporioides, and a Chaetomium species. After inoculation, fungal growth on the polyimides resulted in distinctive EIS spectra indicative of polymer insulation failure, which directly related to polymer integrity. Degradation appeared to occur in a number of steps and two distinctive stages in the decline of film resistance were observed in the inoculated EIS cells within the 2 and 10 weeks after inoculation. The early stage of resistance decrease may be related to the ingress of water molecules and ionic species into the polymeric materials, whereas the second stage probably resulted from partial degradation of the polymers by fungal growth on the polymer film. The relationship between changes of impedance spectra and microbial degradation of the polymer was further supported by scanning electron microscopy (SEM) observations of fungi growing on the surface of the inoculated polyimides. Our data indicate that the EIS can be used in detection of early degradation of resistant polymers and polyimides that are susceptible to biodeterioration. 相似文献
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目的 针对某型船海水管路杂散电流腐蚀穿孔问题,研究海水管路直流杂散电流密度与直流电气设备机壳绝缘电阻关系,评估海水管路直流杂散电流腐蚀风险,提出直流电气设备机壳绝缘电阻要求,为船舶海水管路杂散电流控制提供技术支撑.方法 根据欧姆定律和腐蚀电化学原理,建立船体与海水管路直流杂散电流腐蚀仿真方法,模拟海水管路直管、弯管以及某船海水管路系统结构,以B10铜镍合金极化曲线为边界条件,开展管壁直流杂散电流密度仿真研究,并根据法拉第定律计算直流杂散电流腐蚀速率.结果 直流电气设备接地产生的直流杂散电流大部分流入船体,仅有少部分流入海水管路,正常情况下,机壳绝缘电阻大于1 M?,直流电气设备接地不会导致海水管路发生杂散电流腐蚀.结论 为避免直流电气设备接地造成海水管路杂散电流腐蚀,DC380 V和DC220 V电气设备机壳绝缘电阻应分别不小于211?和123?. 相似文献
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对于慢摇吧低音炮传递的结构噪声,采用新型隔声材料静馨隔声毡,结合岩棉等传统吸声材料,可克服传统吸隔声材料的低频吸隔声效果差和"吻合效应"等弱点,从而有效控制音炮传递的结构噪声。 相似文献
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热防护系统热真空模拟试验技术 总被引:1,自引:1,他引:0
介绍了一种能模拟可重复使用运载器热防护系统内、外表面气动热和压力环境的热真空模拟试验装置,该装置不仅能模拟TPS外表面所受气动热和气动压力条件,还能模拟TPS内表面的真空压力环境。其外部环境压力4.0×10^2-2.0×10^5Pa,内部环境压力4.0~1.013×10^5Pa,热面温度可高达1100℃。利用该装置可以对热防护系统的传热性能进行稳态和瞬态测试。简要介绍了该装置的构成及功能,以及用其进行材料和结构的传热性能测试的试验方法。该装置的研制将为我国高超音速飞行器热防护系统的验证提供必要的技术手段。 相似文献
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In this paper, we present the integrated assessment model dimrise (dynamic integrated model of regular climate change impacts and singular events). This model is designed to investigate the stability of the Atlantic thermohaline circulation (THC) and to derive related
climate policy recommendations. It is written in GAMS and comprises a dynamic model of the THC coupled to a climate model
and a global economy model for assessing the monetary cost of climate protection. The THC model is a dynamic four-box interhemispheric
extension of the classic Stommel model calibrated against results obtained using the CLIMBER-2 climate model. The reduced-form
climate model used to drive the THC model is the ICLIPS multi-gas climate model, which is a computationally efficient, globally
aggregated model able to mimic the response of more sophisticated carbon cycle and atmosphere-ocean general circulation models.
The THC and climate modules are coupled to a globally aggregated Ramsey-type optimal growth model of the world economy derived
from the Nordhaus DICE model. Together, these components create a novel dynamic fully coupled computationally efficient integrated
assessment model. Illustrative applications demonstrate that dimrise is able to derive (constrained) economically optimal emissions paths that comply with prescribed bounds on admissible THC
weakening imposed in order to avoid an irrevocable breakdown. In addition, emissions corridors are presented which contain
all possible emissions paths that do not endanger the stability of the THC and that simultaneously obey restrictions on welfare
loss arising from mitigation efforts. The presented results show that, under worst-case conditions, the stability of the THC
may be threatened within two decades if global emissions would not deviate from the business-as-usual trajectory.
相似文献
K. ZickfeldEmail: |
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